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Chemical storage you
most often use and what you most need to know
by Tom Hammel
It’s a fact of life:
spills happen. Regardless of how or when it happens, how you act
both before and after the event is the key to minimizing damage,
downtime, injuries and penalties.
“Some of the reasons for
a spill can be improper handling of the chemical, whether it’s in
the warehouse or in a laboratory; forklift punctures to chemical
containers; improper storage (lids not properly closed); employee
carelessness and other causes,” says Susan Naser, vice president,
sales and marketing for SpillTech Environmental.
“With any chemical you
need to know its properties, what it is compatible with and what it
will react with. You must make sure like chemicals are stored
together and not with chemicals that would cause an instant
reaction.”
In addition, Naser
advises users to evaluate the consequences of a spill for all
chemicals and have a contingency plan for the proper cleanup of that
chemical — taking into consideration first the safety of your
employees.
Properly responding to a
spill can prevent a minor accident from escalating into a
catastrophe.
General chemical
handling and storage procedures
The following are general safety practices to follow when handling
and storing industrial chemicals. Remember, these are just
commonsense guidelines, not regulations themselves. Standards and
regulations regarding the proper storage and handling, spill cleanup
and hazardous waste disposal are guided by standards maintained by
the National Fire Protection Association (NFDA), OSHA and other
national, regional and municipal regulatory bodies.
Guidelines for specific
chemicals are outlined in MSDS (Material Safety Data Sheet) papers
which are available from chemical suppliers as well as online. Be
sure you have MSDA sheets on hand for every chemical used and stored
in your facility.
Flammable and
combustible chemicals
• Avoid energized equipment and sources of ignition.
If a spill occurs near energized lines or equipment,
kill power in that area and turn off any other possible
sources of ignition
• Use proper grounding and bonding techniques
• Use metal containers whenever possible
• Ensure good ventilation
• Make sure all equipment and tools used on or with
these chemicals are intrinsically safe — those in
which electrical energy is limited such that it will
not spark or otherwise ignite a flammable mixture
• Store only small quantities in flammable storage
cabinets. Quantity limits and arrangements are
specified in OSHA 29 CFR 1910.106 and NFPA 30
• Control temperature & ventilation
• For aerosols, refer to NFPA 30B for proper aerosol
storage levels
Corrosives and
aerosols
• Avoid metal containers
• Avoid skin contact
• Do not heat or freeze containers
• Do not touch to live electricity sources
• Focus aerosol sprays with extension tubes
• Never concentrate and inhale vapors
Communication and
warnings
The best safety storage and handling practices are meaningless
without comprehensive communication.
• Follow all OSHA Hazard Communication guidelines
in the workplace and at exits
• Identify and label all chemicals
• Post hazard warnings
• Include the name, address and contact information
of each chemical’s manufacturer
• Communication signs may use words, pictures or
symbols, but they must be legible and prominently posted
• In addition to English, hazard warnings and
communications must be posted in any other language
common to that workplace
Training fundamentals
1. Make sure that all employees handling or interacting with
chemicals be properly trained on the properties and risks of spills.
2. Train all employees in spill response and how to use the
equipment needed to clean up the spill.
3. Have written guidelines with emergency contacts for when a spill
happens.
4. Audit your spill kits monthly to make sure they are properly
stocked with all the items you might need.
Some chemical suppliers
offer training and handling programs of their own. CRC Industries
offers a program called the MR Chemicals Risk Reduction Partnership
Plan. This program develops individualized best practice action
plans to help industrial customers manage the purchase, use, storage
and disposal of chemicals with maximum safety and cost efficiency.
“Our Risk Reduction
Partnership Plan was created with just these problems in mind,” says
Greg Nieberle, product manager for CRC Industries Inc. “In addition,
our Stoplight Food Safety program helps food industry professionals
in the handling, evaluation and control of maintenance chemicals We
have also created a series of hazard communication training sessions
for user sites, called ‘Safety Shorts,’ which address different
aspects of chemical handling and storage.”
Be prepared
There is nothing quite like the empty feeling when a spill occurs
and you realize too late that you are short on cleanup materials.
Spill kits are available from a number of manufacturers and utilize
products ranging from sand to high-tech materials.
“Our absorbent rolls,
pads, socks, pillows and booms are made of 100 percent polypropylene
because it is compatible with many chemicals,” says SpillTech’s
Naser. “We offer standard kits, but we customize them, too. Plus,
many customers add PPE (gloves, goggles, suits, aprons, etc.) to the
spill kits according to what chemicals might be spilled, thus
customizing them for the areas for which they are intended.”
In addition, SpillTech
products are yellow, which provides workers with a visual warning
that a spill has occurred.
Spilled milk
Ultimately, no matter how well you prepare, chemical spills will
occur. However, following prescribed best practices, training your
workers well and having a conscientious chemical storage program in
place will help keep you from really crying when the inevitable
happens.
First response tactics
Follow these general guidelines when dealing with suspect
spills:
• Report the spill immediately
• Turn off any ignition sources in the area
• Evacuate the area
• Help in the cleanup effort only if you have been
trained in proper procedures and safety precautions
• Wear the correct PPE |
Safe
handling
General guidelines:
• Keep containers closed when not in use
• Use proper ventilation and exhaust
• Use spark-proof equipment and tools
• Take only the amount needed for the job
• Practice good housekeeping habits
• Do not weld or torch empty containers
• Store chemicals in fire-resistant buildings,
rooms and cabinets
• Only use explosion-proof lighting and equipment
in storage areas
• Mark storage areas well with warning signs
• Keep storage areas free of other combustibles
• Avoid stacking containers
• Don’t store incompatible materials in the same
area or cabinet
• Keep storage cabinets cool, well ventilated and
out of direct sunlight
• Keep storage areas and cabinets a safe distance
from electrical panels, furnaces or other heat sources
• Keep in mind maximum storage limits for cabinets,
drums and other containers |
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Must-reads
NFPA 497: Recommended Practice for the
Classification of Flammable Liquids, Gases, or Vapors and of
Hazardous (Classified) Locations for Electrical
Installations in Chemical Process Areas, 2008 Edition
NFPA 499: Recommended Practice for the
Classification of Combustible Dusts and of Hazardous
Locations for Electrical Installations in Chemical Process
Areas, 2008 Edition
NFPA 30: Flammable and Combustible Liquids Code,
2003 Edition
These titles are
available from the National Fire Protection Association at
www.nfpa.org. |
This article appeared in the
April/May 2008 issue of MRO Today magazine. Copyright 2008.
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